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Polyurethane elastomer (CPUE), referred to as casting
polyurethane (CPU) or polyurethane pouring resin. "Pouring type"
refers to a kind of chemical processing method in which the material system of
the product is liquid before molding, which can be poured and solidified
directly, and the material system does not contain volatile liquid in principle.
Because the material system is liquid before molding, while TPU and MPU
products are solid before molding, CPU can also be called liquid rubber or
liquid elastomer. Compared with TPU and MPU, CPU has a wider range of raw
materials and a wider range of product hardness, which is especially suitable
for the production of large and medium-sized products, which makes up for the
limitations and deficiencies of TPU and MPU products processing technology, and
can maximize the performance advantages of polyurethane elastomer and broaden
the application field of polyurethane elastomer.
CPU elastomer first appeared in Germany. In the early
1950s, the world's first CPU product was produced in German Bayer company with
the brand name of Vulkollan. At the end of 1950s, DuPont company of the United
States introduced the polyether type CPU with the commercial brand of adipenel
with PTMG and TDI as the main raw materials, and then MDI CPU appeared, which
made outstanding contributions to the development and application of polyurethane
elastomer. Since the 1970s, new materials such as liquefied MDI, low
unsaturation polyether, low free TDI prepolymer, amino terminated polyether and
various environmental friendly amine chain extenders have successively entered
the market. Reaction injection molding (RIM) and spray polyurea elastomer
technology have been introduced one after another, which greatly promotes the
traditional CPU product molding technology and broadens the application field
of CPU products.
In addition to the traditional CPU, TPU and MPU,
polyurethane elastomer should also include waterproof coating and paving
materials, sole stock solution, synthetic leather slurry, spandex and adhesive,
because they are in high elastic state (rubber state) at room temperature. Among
them, waterproof and paving materials, sole stock solution are liquid before
product forming, without solvent, which should be attributed to CPU. According
to this classification, the consumption of polyurethane elastomer in China was
about 870000 tons in 2005, which was close to 40% of the total consumption of
polyurethane in China. Among the elastomers, the CPU consumption was 360000
tons, accounting for 41.3%. Among them, 200000 tons of rim products, 100000
tons of paving materials, 60000 tons of traditional CPU, accounting for 17%.
The sole stock solution belongs to microporous elastomer.