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The size shrinkage of cast polyurethane products is mainly based on the following two reasons.
When the pouring
material changes from liquid to solid, the molecular cohesion increases, which
makes the product size smaller.
The thermal
expansion coefficient of the casting material is larger than that of the mold
material. The resulting size shrinkage increases with the increase of the
molding temperature, that is, the higher the molding vulcanization temperature,
the greater the size shrinkage. The size shrinkage of products cured at room
temperature is minimal.
In addition, the
shrinkage rate is also related to the shape and size of the product, and the
hardness of the product. The shrinkage rate of products in different directions
is also different, and the shrinkage of hard products is generally slightly
larger than that of soft products. Products with a metal skeleton shrink less
and shrink toward the metal. The shrinkage rate is related to many factors,
among which the molding vulcanization temperature is most easily overlooked. It
is often found that the size of the products formed by the same mold is quite
different, most of which are caused by the fluctuation of the molding
vulcanization temperature. In addition, according to the author's many years of
practice, the size of vulcanized products varies greatly, mostly caused by
fluctuations in the molding vulcanization temperature. In addition, according
to the author's many years of practice, the length of vulcanization time, hot
and cold demolding, atmospheric vulcanization, pressure vulcanization, etc.
will also affect the shrinkage of the product. Therefore, for products with
strict size requirements, in addition to strictly controlling the molding and
vulcanization temperature, other operations must also be standardized.
The shrinkage
rate of CPU elastomer moldings is generally 1% to 2%. It can be designed
according to 1.5% to 1.7% first, and there is a certain margin for modification
in the key dimensions of the mold. In addition, the vulcanization molding
temperature (such as 100-120°C) can be appropriately changed to adjust the
shrinkage rate of the product within a certain range.